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BIOLOGICAL FILTRATION
General Remarks
What biological filtration is all about, is not the
subject matter of this book. You may wish to refer to general
marine aquarium books if you are not entirely familiar with
biological filtration, or if you want to read up on it some more.
One not-general-at-all book, but a very detailed one on
marine aquarium systems that we highly recommend is _The Marine
Aquarium Reference-Systems and Invertebrates_, by Martin Moe,
1989. It contains a wealth of information that you will be
interested in, as well as many practical tips and advice that you
will be able to put to good use. Besides that, it explains a lot
of the more theoretical concepts in clear language,
understandable by the average Hobbyist.
Biological filtration is a very important component of
your total filtration system. As most of you know, breakdown
products of metabolism and decay of protein, produce either
ammonium ion or ammonia depending on the pH of the medium .
In a marine environment where the pH is relatively high,
a percentage of this ammonium ion is in the form of ammonia, a
very soluble and toxic gas. Even very small amounts of NH3 are
extremely toxic and will cause great stress to the fish and
invertebrates, killing some of them off, which creates more
pollution and more stress.
To remove this ammonia and ammonium ion nature, comes to
our help with the nitrification process, whereby ammonia is
converted to nitrite, and nitrite to nitrate by bacteria that
will grow spontaneously in the tank, or that can be added
(seeding) when first starting up the tank, to speed up their
proliferation.
Bacteria grow everywhere, not just in a biological
filter. Please keep that in mind. The size of the bacterial
population is also determined by the amount of nutrient available
to them. Keep that in mind too. Most Hobbyists do not, and think
that once their filter is cycled, they can put a large number of
fish and invertebrates in the tank, without danger, and
immediately.
That is not so ! It is a mistake very often made, and it
leads to die-offs, disease, stress, and a host of problems. Look
at it this way : a biological filter that is very potent during
the cycle, can only keep sustaining the same amount of pollution
as it had during the cycle. If you increase the load in the tank
to beyond that level, the filter has to readjust and build up
even more bacteria.
To simplify the explanation : if you had 5 pieces of
so-called live rock in the tank during the first 4 weeks
(i.e.during the cycle), and it required, for argument's sake, 7
million bacteria to cope with the pollution so generated, you
cannot expect those same 7 million bacteria to cope with 10
pieces of live rock (keep in mind that the numbers are arbitrary
and bear no relationship to the real numbers. They are only used
to illustrate a point).
To cope with this new load you will need even more
bacteria. They will grow spontaneously in your filter, but it
will take a few days for them to appear and neutralize the
increased amount of ammonia (and subsequently the higher amount
of nitrite).
Each time you add an animal or an invertebrate, more
ammonia is generated and more bacteria are necessary in the
filter to neutralize that pollution. That is the reason for the
often found recommendation : add new tank inhabitants only a few
at a time, and wait several days between each introduction ( your
safest bet is to check for ammonia and nitrite, if none is found
you can add more lifeforms).
Indeed, doing so let's the filter catch up (meaning more
bacteria grow) without creating undue stress on the animal life
already in the tank. This results in a safe and gradual increase
in the tank's population. If, in addition, you use the
recommended methods for adding fish and inverts, you should not
have any problems with outbreaks of parasitic infestations.
No one can offers 100 percent guarantees, but if you
follow these recommendations, your chances of not getting any
parasites will be greatly improved. You are, then, also less
likely to lose the animals (and the money they cost you). Marine
Reef, the newsletter, featured several articles on this subject
already.
A similar remark applies to biological filters that are
started up with several rocks or fish, and then left to run with
far less lifeforms for a while. The filter adjusts to the lower
amount of pollution. If the Hobbyist then decides to place a
larger number of lifeforms in the tank again, the filter will not
be able to cope with this increased load. It will need to
readjust first, and that takes time. If you do not let the
filter adjust, stress will be created and lifeforms will be lost
(or as often is the case, disease will break out).
This is an important remark to remember with regard to
biological filters ! How long the readjustment phase will take
cannot be predicted. Testing for ammonia and nitrite is the only
sure way to deter-mine whether or not the filter is ready for an
increased load. Both should test zero ppm (or mg/l).
We noted that mechanical filtration is important for two reasons :
Correct biological filtration is very important because it :
Incidentally, and as a reminder that trickle filters are
not some recent development, the first reference to such filters
that I could find is in a book published in 1935, yes that long
ago, called American Sewerage Practice, by Leonard Metcalf and
Harrisson Eddy, Volume 3 of 3, The Maple Press Company, York,
Penna. Call them if you are interested in how large volumes of
water get treated. That book was brought to my attention by
Matthew Cammarata.
The filters in that book are large, some even very large,
at least compared to what we use in the Hobby nowadays, but the
principle behind their efficiency has not changed an iota over
the years.
Such biological filters (not necessarily all trickle
filters) can be set up in many ways. All work of course, or
Hobbyists would not have used them for several years now, and
they would not be around in the literature anymore.
There are however varying degrees of efficiency in the
types, brands and models available on the market. Some just do a
better job than others. You know most of them :
There are other types of biological filters too, perhaps
not as familiar to you, but they are used by a fair number of
Hobbyists too:
All of them serve the same purpose : the three reasons
stated above. As indicated, however, some of these filters do a
much better job than others at improving water quality,
especially where it comes to re-oxygenating the tank's water.
For years in the hobby, especially in Europe, the trickle
filter has made great strides in this country too. In 1985, when
I first imported trickle filters from Germany (from a company
called Nollman Aquaristik, in Sennestadt), hardly anybody even
knew what such filters looked like, or what they were supposed to
do. Nowadays, just looking at the ads in the Hobby magazines,
everyone seems to claim "they" were the first to ever offer this
type of filter (refer too to my earlier remark about the 1935
reference to trickle filters in _American Sewerage Practice_ to
convince yourself that such is merely advertising copy).
Who was the first, and when, is not important and
germane, what counts is that these filters are extremely
efficient, and that for the purpose we are interested in - high
quality water - they are the foremost filter, and the most
effective at the present time. The variety and number of such
filters now available attests to their success, and to the fact
that both manufacturers, and Hobbyists alike, believe in them.
Because I strongly believe that to run a successful Reef you need
such a filter, or a similar type e.g. a hang-on unit (Ruecksack
or some types of conversion units, for instance), we will review
only such filters in this section. Information on undergravel,
and similar filters, can be found in many other books, as I am
sure you are aware of. Refer to them if you still want more details,
or if you want to review and compare them with trickle filtration.
Inside an appropriate compartment, a medium is placed on
which Nitrosomonas and Nitrobacter can grow in large numbers. The
shape of the box has absolutely no bearing whatsoever on the
efficiency of the filter, although most manufacturers make them
square or rectangular, because round tube or pipe of the size
usually required, would make the filter much more expensive.
When dealing with the shape of a trickle filter, the
important factors to take into account are the following, in my
opinion:
filters that are too narrow tend to create "channeling" of the
water against the outside panels of the filter, resulting in very
inefficient use of the medium,
filters that are short, meaning not tall enough, do not
promote re-oxygenation very well, and are therefore not as
desirable. The minimum suggested height of the column of
biological medium is 12 to 14 inches.
Most filters you see are clear, probably because clear
acrylic is less expensive than other varieties. In fact, the
filter would do better if it was not clear, as the bacteria
perform better in the dark (documented in too many articles to
mention). Nollman Aquaristik, of Sennestadt Germany, which has
been building filters for many more years than anyone in the USA,
builds theirs in opaque PVC sheet. Luebbecke Aquarium who have
used large trickle filters on their 10.000+ gallon system for
many years, uses 3 foot diameter grey PVC pipeline sections.
Another reason may be that clear filters can easily be
looked into, something the Hobbyist likes to do, to determine how
the water is flowing through the medium.
The biological filter compartment should be removable
from the other parts of the filter. This allows for easier
transport and shipping, easier installation, and much easier
cleaning of the other parts of the filter when the need arises
(and it will, believe me, mainly because most filters on the
market do not have slanted bottoms which will require you to
syphon out detritus from time to time).
As the water comes down from the tank to the filter, and
disperses inside the biological chamber, it travels over the
medium and allows the bacteria that grow on them to polish the
water by first converting ammonia to nitrite (one type of
bacterium) and then from nitrite to nitrate (another bacterium).
The better the dispersion of the water, the
better the water is spread over the medium, and the better the
filter will be able to clean up the water. That should be
obvious. Not only is filtration more efficient, but by using the
medium more efficiently you will need less of it. This can save
you quite a few dollars as most of the media are still relatively
expensive.
Additionally, less medium fits in a smaller filter, and
that too will save you money. It will also make more space
available underneath the aquarium, and since space there is at a
premium....
Because you do not want to have to clean the biological
filter - in doing so you would destroy a large amount of bacteria
- the medium should allow a good throughflow of water, and not
trap dirt that may have slipped through your fine filters
(mechanical filtration). It isn't supposed to, but some will. If
it gets stuck in the medium, in the long run you are looking at
cleaning it. We already stated that such is not desirable at all.
Dense material will plug up no matter how well you
filter. The main reasons for this is that fine particulate matter
not trapped in the fine filters will eventually clog certain
areas of your dense biological filter, creating anoxic pockets.
When oxygen levels are low, or non-existent, decay is proceeding
anaerobically, and hydrogen sulfide is produced. This will pull
your water quality down very quickly.
In fact, if you were measuring redox potential levels,
and they are low, even though you are using a considerable amount
of ozone, the likely reason is that small amounts of hydrogen
sulfide are pulling the redox down, because of the reductive
power of hydrogen sulfide. Increasing the ozone may not even
help. You must eliminate the H2S to bring the redox potential
back up. There exist of course many other reasons for low redox
potential, some of them will be covered elsewhere in this book,
especially in the Maintenance Section.
it removes particulate matter before it can break down and
pollute the water,
it makes the tank look more appealing, by unclouding the
water and removing debris. breaks down ammonia to nitrite (Nitrosomonas bacteria)
breaks down nitrite to nitrate (Nitrobacter bacteria)
oxygenates the water for the benefit of all lifeforms and the
filter itself.
removes a number of unwanted compounds through facultative
aerobic-anaerobic activity in portions of the filter (Wolff
1984). Canister filters, traditional
Canister filters, special
Undergravel filters, regular flow, reverse flow
Outside box filters
Trickle filters in many configurations
and a combination of one or more of the above. BioMesh filters
Ruecksack or Backpack filters (hang-on trickle
filters)
Tray Filters, similar to trickle filters
Outside the tank biological sand filters
and a variety of intermediate ones, based on the sand
filter system.
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